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This is the result.
Let's create a Vignette. Create a new layer. Pick a dark color from the background and paint on the edges of the manipulation. Set the layer to Soft Light (Opacity and Fill 80%) and add a bit of Gaussian Blur if you want.
Let's add a bit of contrast so that Lights and Shadows will be more interesting.
Create a Curve adjustment layer and set the Medium Contrast from the Preset Curves. On the white mask of this layer paint with a black brush on th face of the lady because it would be too dark. Set the layer to Luminosity and the Opacity to 70%.